Have you tried as below :
ALTER TABLE Table
ALTER (Column Data_Type DEFAULT Default_Value,
Column Data_Type NULL);
Also below one :
ALTER TABLE
You can change the definition of an existing column.
For columns without a default value, you can specify one.
For columns with a default value, you can change the existing value.
The new (or first time) defined default value only affects newly inserted rows.
For columns that do not allow NULL values so far, NULL values can be allowed.
ALTER TABLE Official
ALTER (Overtime INTEGER DEFAULT 7,
Salary VARCHAR(3) DEFAULT 'A01',
Name VARCHAR(20) NULL);